HCID 25258107, 화합물 → HCID 59379786, 화합물

HRID 908116

반응식

HRID 908116 반응식
[Br:1][C:2]([CH3:25])([CH3:24])[C:3](C1C=CC(C23CCC(CC(OC)=O)(CC2)CC3)=CC=1)=[O:4].[C:26]1([C:32]23[CH2:41][CH:36]4[CH2:37][CH:38]([CH2:40][C:34]([CH2:42][C:43]([O:45][CH3:46])=[O:44])([CH2:35]4)[CH2:33]2)[CH2:39]3)[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1>>[Br:1][C:2]([CH3:25])([CH3:24])[C:3]([C:29]1[CH:28]=[CH:27][C:26]([C:32]23[CH2:41][CH:36]4[CH2:37][CH:38]([CH2:40][C:34]([CH2:42][C:43]([O:45][CH3:46])=[O:44])([CH2:35]4)[CH2:33]2)[CH2:39]3)=[CH:31][CH:30]=1)=[O:4]

참가 물질

3

반응물 2

HCID 25258107HCID 25258107, 화합물HCID 53665692Methyl 3-phenyl-1-adamantaneacetate

생성물 1

HCID 59379786HCID 59379786, 화합물수율 35%

실험 절차

Prepared according to the procedure described for Intermediate 9 using methyl (3-phenyl-1-adamantyl)acetate, the title compound being isolated in 35% yield: 1H NMR (CDCl3) δ 1.66 (d, 4H), 1.71 (s, 2H), 1.77 (s, 2H), 1.87 (s, 4H), 2.04 (s, 6H), 2.18 (s, 2H), 2.20-2.22 (m, 2H), 3.65 (s, 3H), 7.41 (d, 2H), 8.12 (d, 2H); GC-MS CI m/e MH+ 433.

후처리

  1. customPrepared

출처 및 근거

ORD 기록
ord-e06bc9ffd35a49d4a9b7925493953fdf
출처 데이터셋
uspto-grants-2011_09
특허 번호
US08017603B2

연결된 노트

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