tert-Butoxy bis(dimethylamino)methane → HCID 67406834, 화합물

HRID 908345노트

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HRID 908345 반응식
[C:1]([Si:5]([CH3:15])([CH3:14])[O:6][C:7]1[C:8](=[O:13])[CH2:9][CH2:10][CH2:11][CH:12]=1)([CH3:4])([CH3:3])[CH3:2].CC(O[CH:21](N(C)C)[N:22]([CH3:24])[CH3:23])(C)C>C1(C)C=CC=CC=1>[C:1]([Si:5]([CH3:15])([CH3:14])[O:6][C:7]1[C:8](=[O:13])[C:9](=[CH:21][N:22]([CH3:24])[CH3:23])[CH2:10][CH2:11][CH:12]=1)([CH3:4])([CH3:3])[CH3:2]

참가 물질

4

반응물 2

HCID 79885tert-Butoxy bis(dimethylamino)methaneHCID 117463392-Cyclohexen-1-one, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-

생성물 1

HCID 67406834HCID 67406834, 화합물

시약·촉매·용매 1

HCID 1140Toluene용매

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온도
115 °C

실험 절차

A mixture of 2-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone (6.9 g, 30.48 mmol) in dry toluene (50 mL) was treated with Bredereck's reagent (9.44 ml, 45.72 mmol) was stirred at 115° C. for 24 hours. The mixture was concentrated under reduced pressure to give 2-(tert-butyl-dimethyl-silanyloxy)-6-dimethylaminomethylene-cyclohex-2-enone as a semi-solid brown residue which was used as such in the next step.

후처리

  1. concentrationThe mixture was concentrated under reduced pressure

출처 및 근거

ORD 기록
ord-b4c7bc6ca22748b9821c0fa65318b344
출처 데이터셋
uspto-grants-2011_09
특허 번호
US08017619B2

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