참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 1-Octanol | HCID 957 | — |
| 반응물 | Isopropenyl acetate | HCID 7916 | — |
| 반응물 | Sodium Carbonate | HCID 10340 | — |
| 반응물 | Tetrafluoroborate | HCID 26255 | — |
| 반응물 | 2,2-Bis(1-octyloxy)propane | HCID 14118151 | — |
| 반응물 | 1-Octyl isopropenyl ether | HCID 22034535 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | Octyl Acetate | HCID 8164 | — |
반응 단계
To a mixture of bis(1,5-cyclooctadiene)iridium tetrafluoroborate [Ir(cod)2]+BF4− (0.01 mmol) and sodium carbonate (0.03 mmol) in toluene (1.0 ml), 1-octanol (130 mg, 1 mmol) and isopropenyl acetate (5 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 15 hours. The reaction mixture was analyzed by gas chromatography to find that 1-octyl isopropenyl ether, 2,2-bis(1-octyloxy)propane, and octyl acetate were produced in yields of 67%, 6%, and 14%, respectively, with a conversion from 1-octanol of 93%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07271297B2 |
|---|
| 출처 데이터셋 | uspto-grants-2007_09 |
|---|
| ORD ID | ord-9f95ec1e57fc4021aa36f56642167b1e |
|---|
| 출처 메모 | uspto-grants-2007_09 |
|---|
