참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 1-Octanol | HCID 957 | — |
| 반응물 | Vinyl Acetate | HCID 7904 | — |
| 반응물 | Octyl Acetate | HCID 8164 | — |
| 반응물 | Sodium Carbonate | HCID 10340 | — |
| 반응물 | 1-(Vinyloxy)octane | HCID 70249 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 1-(1-Octyloxy)ethyl acetate | HCID 22034537 | — |
반응 단계
To a mixture of di-1-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (0.01 mmol) and sodium carbonate (0.1 mmol) in toluene (1.0 ml), 1-octanol (130 mg, 1 mmol) and vinyl acetate (5 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 2 hours. The reaction mixture was analyzed by gas chromatography to find that 1-octyl vinyl ether, octyl acetate, and 1-(1-octyloxy)ethyl acetate were produced in yields of 58%, 3%, and 21%, respectively, with a conversion from 1-octanol of 100%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07271297B2 |
|---|
| 출처 데이터셋 | uspto-grants-2007_09 |
|---|
| ORD ID | ord-9ae999423ea0441593e4508c7b2c6acf |
|---|
| 출처 메모 | uspto-grants-2007_09 |
|---|
