Potassium Carbonate → 1-Amino-2-(3'-methyl-5'-hydroxypentanoxy)-4-hydroxyanthraquinone

HRID 917885

반응식

HRID 917885 반응식
[NH2:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5]([OH:18])=[CH:4][C:3]=1[O:19][C:20]1C=CC=C[CH:21]=1.[CH3:26][CH:27](CCO)[CH2:28][CH2:29][OH:30].C(=O)([O-])[O-].[K+].[K+]>CN1CCCC1=O>[NH2:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5]([OH:18])=[CH:4][C:3]=1[O:19][CH2:20][CH2:21][CH:27]([CH3:26])[CH2:28][CH2:29][OH:30]

참가 물질

5

반응물 3

HCID 11430Potassium CarbonateHCID 205243-Methyl-1,5-pentanediolHCID 28531Disperse Red 60

생성물 1

HCID 215241071-Amino-2-(3'-methyl-5'-hydroxypentanoxy)-4-hydroxyanthraquinone

시약·촉매·용매 1

HCID 13387N-methyl-2-pyrrolidone용매

실험 절차

12.5 parts of 1-amino-2-phenoxy-4-hydroxyanthraquinone, 13 parts of 3-methyl-1,5-pentanediol, 25 parts of N-methylpyrrolidone, 3 parts of polyethylene oxide of average molecular weight 300 and 2 parts of anhydrous potassium carbonate are stirred for one hour at 150°C under nitrogen. After working up, 10.5 parts of 1-amino-2-(3'-methyl-5'-hydroxypentanoxy)-4-hydroxyanthraquinone are obtained.

출처 및 근거

ORD 기록
ord-980b59c6845f401095d3ecc891f9df97
출처 데이터셋
uspto-grants-1976_07
특허 번호
US03968131

연결된 노트

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