Benzene → N,N-diethyl 3,7,11-trimethyldodeca-2,4,10-trienylamine

HRID 918332노트

반응식

HRID 918332 반응식
Cl[C:2]([CH3:17])([CH3:16])[CH2:3][CH2:4][CH2:5][CH:6]([CH3:15])[CH2:7][CH:8]=[CH:9][C:10]([CH3:14])=[CH:11][CH2:12]Br.BrCC=C(C)C=CCC(C)CCC=C(C)C.C1C=CC=CC=1.[CH2:40]([NH:42][CH2:43][CH3:44])[CH3:41]>C(Cl)Cl>[CH2:40]([N:42]([CH2:12][CH:11]=[C:10]([CH3:14])[CH:9]=[CH:8][CH2:7][CH:6]([CH3:15])[CH2:5][CH2:4][CH:3]=[C:2]([CH3:17])[CH3:16])[CH2:43][CH3:44])[CH3:41]

참가 물질

6

반응물 4

HCID 241BenzeneHCID 8021DiethylamineHCID 5387143211-Chloro-3,7,11-trimethyldodeca-2,4-dienyl bromideHCID 54370561HCID 54370561, 화합물

생성물 1

HCID 53837124N,N-diethyl 3,7,11-trimethyldodeca-2,4,10-trienylamine

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

Five grams of 1 bromo-3,7,11-trimethyldodeca-2,4,10-triene in 25 ml. of benzene is mixed with 4 g. of diethylamine and the mixture stirred for about three hours. Methylene chloride (50 ml.) is added and the mixture washed with dilute sodium hydroxide and then water and evaporated to yield N,N-diethyl 3,7,11-trimethyldodeca-2,4,10-trienylamine.

후처리

  1. washthe mixture washed with dilute sodium hydroxide
  2. customwater and evaporated

출처 및 근거

ORD 기록
ord-fd1ec86af4c24fd3b2e9cc477e948b13
출처 데이터셋
uspto-grants-1976_07
특허 번호
US03970704

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