5-Nitrofuroyl chloride → HCID 86664239, 화합물

HRID 919383노트

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HRID 919383 반응식
[N+:1]([C:4]1[O:8][C:7]([C:9](Cl)=[O:10])=[CH:6][CH:5]=1)([O-:3])=[O:2].[NH:12]([C:14]1[S:15][C:16]2[CH:22]=[C:21]([CH3:23])[CH:20]=[CH:19][C:17]=2[N:18]=1)[NH2:13]>>[CH3:23][C:21]1[CH:20]=[CH:19][C:17]2[N:18]=[C:14]([NH:12][NH:13][C:9]([C:7]3[O:8][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][CH:6]=3)=[O:10])[S:15][C:16]=2[CH:22]=1

참가 물질

3

반응물 2

HCID 907115-Nitrofuroyl chlorideHCID 20498392-Hydrazinyl-6-methyl-1,3-benzothiazole

생성물 1

HCID 86664239HCID 86664239, 화합물

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온도
0 °C

실험 절차

The compound 4b was prepared according to above described method by using 5-nitro-2-furancarboxylic acid chloride (300 mg, 1 mmol) and 2-hydrazino-6-methylbenzothiazole (179 mg, 1 mmol) which stirred for 1 h at 0° C. and stirring continued at 25° C. for 11 h (yield 216 mg, 85%).

후처리

  1. stirringstirring
  2. waitcontinued at 25° C. for 11 h

출처 및 근거

ORD 기록
ord-3bfd09b4841a4114b0b0a92b29d6b188
출처 데이터셋
uspto-grants-2016_03
특허 번호
US09273039B2

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