Zinc → Zinc pivalate

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[C:1]([O-:7])(=[O:6])[C:2]([CH3:5])([CH3:4])[CH3:3].FC(F)(F)C1C=C([Zn+:16])C=CC=1.[Zn]>>[C:1]([O-:7])(=[O:6])[C:2]([CH3:5])([CH3:4])[CH3:3].[Zn+2:16].[C:1]([O-:7])(=[O:6])[C:2]([CH3:5])([CH3:4])[CH3:3]

참가 물질

반응물 2

HCID 23994Zinc2회

HCID 178447605HCID 178447605, 화합물

생성물 1

HCID 19435776Zinc pivalate

실험 절차

The 3-(trifluormethyl)phenylzinc pivalate (1d) product can be stored under inert gas atmosphere at ambient temperature for one week without any loss of activity (entry 1, Table 1 below). After 5 minutes of storage in air, 95% of active zinc species could be determined by titration (Table 1, entry 2). After 15 minutes, the activity is reduced to 58% (Table 1, entry 3) and after 30 and 45 minutes, activities of 43% and 40% are obtained (Table 1, entries 4-5). After storage on air for 60 minutes, active zinc species cannot be detected (Table 1, entry 6).

후처리

customafter 30 and 45 minutes, activities of 43% and 40% are obtained (Table 1, entries 4-5)
waitAfter storage on air for 60 minutes

출처 및 근거

ORD 기록: ord-7e49b1a1a2de437692cf054654b8da5a
출처 데이터셋: uspto-grants-2016_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09273070B2

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