HCID 14245847, 화합물 → HCID 428467, 화합물

HRID 921511노트

반응식

HRID 921511 반응식
[H-].[H-].[H-].[H-].[Li+].[Al+3].[CH:7]([NH:9][CH2:10][C:11]([CH3:17])([CH3:16])[CH2:12][NH:13][CH:14]=O)=O>CCOCC>[CH3:7][NH:9][CH2:10][C:11]([CH3:17])([CH3:16])[CH2:12][NH:13][CH3:14]

참가 물질

4

반응물 2

HCID 14245847HCID 14245847, 화합물HCID 21226445Aluminium lithium hydride

생성물 1

HCID 428467HCID 428467, 화합물

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

To a mixture of 250 mL of ether and 10 g of LiAlH4 (95%) at 0° C., 9.88 g (62.5 mmol) N,N′-diformyl-2,2-dimethylpropane-1,3-diamine was added in small portions. After the addition, the reaction mixture was stirred at room temperature for 20 h. The mixture was then hydrolyzed with ether and water, the white solid removed by filtration through Celite, and the filtrate dried over anhydrous Na2SO4. After removal of the solvent, the product was obtained as a colorless oil. MS (m/e): 131 (M+).

후처리

  1. additionAfter the addition
  2. customhydrolyzed with ether and water, the white solid removed by filtration through Celite
  3. dry with materialthe filtrate dried over anhydrous Na2SO4
  4. customAfter removal of the solvent
  5. customthe product was obtained as a colorless oil

출처 및 근거

ORD 기록
ord-cf41ee942e22437eb95d69e2f78610fb
출처 데이터셋
uspto-grants-2016_03
특허 번호
US09273343B2

반응 노트

불러오는 중…