Diglycerin → Diglycerol mono-ricinoleate diglycerol di-ricinoleate

반응식

C(O)C(O)C[O:4][CH2:5][CH:6]([OH:9])[CH2:7][OH:8].[C:12]([OH:32])(=[O:31])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][C@@H:23]([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[OH:24]>>[C:12]([OH:32])(=[O:31])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][C@@H:23]([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[OH:24].[OH:4][CH2:5][CH:6]([CH2:7][OH:8])[OH:9].[OH:4][CH2:5][CH:6]([CH2:7][OH:8])[OH:9].[C:12]([OH:32])(=[O:31])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][C@@H:23]([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[OH:24].[C:12]([OH:32])(=[O:31])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][C@@H:23]([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH3:30])[OH:24].[OH:4][CH2:5][CH:6]([CH2:7][OH:8])[OH:9].[OH:4][CH2:5][CH:6]([CH2:7][OH:8])[OH:9]

참가 물질

반응물 2

HCID 42953Diglycerin

HCID 643684Ricinoleic Acid

생성물 1

HCID 131735033Diglycerol mono-ricinoleate diglycerol di-ricinoleate

실험 절차

From table 7a it appears that for esters of diglycerol and ricinoleic acid optimum wearing reduction is provided with a molar ratio diglycerol mono-ricinoleate/diglycerol di-ricinoleate of about 1.15.

출처 및 근거

ORD 기록: ord-b586272e42a149a2b3adcc042b4fbcde
출처 데이터셋: uspto-grants-2016_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09290434B2

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