Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzene → Cyclohexyl acetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzene | HCID 241 | — |
| 반응물 | Cyclohexanol | HCID 7966 | — |
| 반응물 | Ethyl Acetate | HCID 8857 | — |
| 촉매 | Ruthenium | HCID 23950 | — |
| 생성물 | Cyclohexyl acetate | HCID 12146 | — |
반응 단계
When a benzene solution containing 15 mmols of cyclohexanol, 5 mmols of ethyl acetate and 0.05 mmols of complex 1 was refluxed under argon atmosphere, GC analysis after 28 hrs showed that all of the ethyl acetate disappeared and cyclohexyl acetate was formed as a single product (Table 8, entry 1). 1H NMR and GC-MS of the isolated product were identical to cyclohexyl acetate prepared by refluxing neat acetic anhydride with cyclohexanol.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09290441B2 |
| 출처 데이터셋 | uspto-grants-2016_03 |
| ORD ID | ord-94025d6f8b0e416db512913c31d4ab47 |
| 출처 메모 | uspto-grants-2016_03 |