Dichloromethane → HCID 58081285, 화합물

반응식

[O:1]=[S:2]1(=[O:13])[CH2:6][CH2:5][C:4]2[CH:7]=[C:8]([CH2:11][OH:12])[CH:9]=[CH:10][C:3]1=2.C(Cl)Cl>>[O:1]=[S:2]1(=[O:13])[CH2:6][CH2:5][C:4]2[CH:7]=[C:8]([CH2:11][O:12][S:2]([CH3:3])(=[O:13])=[O:1])[CH:9]=[CH:10][C:3]1=2

참가 물질

반응물 2

HCID 6344Dichloromethane

HCID 17966965HCID 17966965, 화합물

생성물 1

HCID 58081285HCID 58081285, 화합물

실험 절차

To a solution of (1,1-Dioxo-2,3-dihydro-1H-1lambda*6*-benzo[b]thiophen-5-yl)-methanol (crude, 160 mg, 0.64 mmol) and triethylamne (180 ul, 1.29 mmol) in DCM (7 ml) Methanesulfonylchloride (60 ul, 0.77 mmol) was added at rt. The reaction mixture was stirred at it for 3 hours.

출처 및 근거

ORD 기록: ord-d527cf76fa4b4b75a7248d1d8db795d9
출처 데이터셋: uspto-grants-2016_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US09290485B2

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