Carbon Tetrachloride → 1-[4-(2-Benzyloxyethoxy)phenyl]-1,2-bis-(4-benzyloxyphenyl)-4-chlorobut-1-ene

반응식

[C:52]([Cl:53])([Cl:54])([Cl:55])[Cl:56].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][CH2:9][CH2:10][O:11][c:12]1[cH:13][cH:14][c:15]([C:18](=[C:19]([CH2:20][CH2:21][OH:22])[c:23]2[cH:24][cH:25][c:26]([O:29][CH2:30][c:31]3[cH:32][cH:33][cH:34][cH:35][cH:36]3)[cH:27][cH:28]2)[c:37]2[cH:38][cH:39][c:40]([O:43][CH2:44][c:45]3[cH:46][cH:47][cH:48][cH:49][cH:50]3)[cH:41][cH:42]2)[cH:16][cH:17]1.[PH3:51]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][CH2:9][CH2:10][O:11][c:12]1[cH:13][cH:14][c:15]([C:18](=[C:19]([CH2:20][CH2:21][Cl:53])[c:23]2[cH:24][cH:25][c:26]([O:29][CH2:30][c:31]3[cH:32][cH:33][cH:34][cH:35][cH:36]3)[cH:27][cH:28]2)[c:37]2[cH:38][cH:39][c:40]([O:43][CH2:44][c:45]3[cH:46][cH:47][cH:48][cH:49][cH:50]3)[cH:41][cH:42]2)[cH:16][cH:17]1

참가 물질

반응물 3

HCID 5943Carbon Tetrachloride

HCID 24404Phosphine

HCID 537217944-[4-(2-Benzyloxyethoxy)phenyl]-3,4-bis-(4-benzyloxyphenyl)-but-3-en-1-ol

생성물 1

HCID 543439551-[4-(2-Benzyloxyethoxy)phenyl]-1,2-bis-(4-benzyloxyphenyl)-4-chlorobut-1-ene

출처 및 근거

ORD 기록: ord-56f0faf3d2e74ab2a70a88d84fdda3b2
출처 데이터셋: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

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