Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acrylonitrile → 3-(3-Iodo-phenylamino)-propionitrile
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acrylonitrile | HCID 7855 | — |
| 반응물 | 3-Iodoaniline | HCID 12271 | — |
| 촉매 | Cupric acetate | HCID 8895 | — |
| 생성물 | 3-(3-Iodo-phenylamino)-propionitrile | HCID 19081634 | 37% |
반응 단계
13at) 4.38 g of 3-iodoaniline, 1.06 g of acrylonitrile and 0.5 g of copper-(II)acetate are mixed and held at 70° for 5 hrs. The mixture is chromatographed on silica gel with ethyl acetate/cyclohexane 1:4 and yields 2.01 g of 3-(3-iodo-phenylamino)-propionitrile as a brown oil. Yield: 37%. Mass spectrum: peak inter alia at m/e : 272 (M+, 50%), 232 (100%); 105 (35%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05763450 |
| 출처 데이터셋 | uspto-grants-1998_06 |
| ORD ID | ord-c87e1452187a472ab805a0aa8f596f49 |
| 출처 메모 | uspto-grants-1998_06 |