Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → Ethyl{4-[2-(5-bromothien-2-yl)ethoxy]-2-methylphenoxy}acetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Bromine | HCID 24408 | — |
| 반응물 | Ethyl[2-methyl-4-(2-thien-2-ylethoxy)phenoxy]acetate | HCID 21986308 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 생성물 | Ethyl{4-[2-(5-bromothien-2-yl)ethoxy]-2-methylphenoxy}acetate | HCID 21986453 | — |
반응 단계
A solution of ethyl[2-methyl-4-(2-thien-2-ylethoxy)phenoxy]acetate (intermediate 69, 0.306 g) in acetic acid (5 ml) was treated with bromine (0.180 g) at ambient temperature and the mixture stirred for 15 minutes. The mixture was poured into water and the resulting suspension extracted with diethyl ether. The organic layer was separated, dried over sodium sulfate and concentrated to give the title compound as a colourless oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07091237B2 |
| 출처 데이터셋 | uspto-grants-2006_08 |
| ORD ID | ord-7637624903df403d86dd6f4ca5b896ea |
| 출처 메모 | uspto-grants-2006_08 |