참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Azobisisobutyronitrile | HCID 6547 | — |
| 반응물 | Methyl Methacrylate | HCID 6658 | — |
| 반응물 | Glycidyl methacrylate | HCID 7837 | — |
| 반응물 | 3-Hydroxypropyl methacrylate | HCID 17694 | — |
| 반응물 | 2-(Toluene-4-sulfonyloxy)ethyl acrylate | HCID 22292251 | — |
| 용매 | Tetrahydrofuran | HCID 8028 | — |
| 생성물 | Glycidyl methacrylate | HCID 7837 | — |
| 생성물 | 2-(Toluene-4-sulfonyloxy)ethyl acrylate 3-hydroxypropyl methacrylate | HCID 86759872 | — |
반응 단계
In a 500 ml round-bottom flask was placed 0.3 mole of 2-(toluene-4-sulfonyloxy)ethyl acrylate, 0.23 mole of 3-hydroxypropyl methacrylate, 0.1 mole of methyl methacrylate, 0.3 mole of glycidyl methacrylate, 300 g of tetrahydrofuran (THF), and 0.1 g-3 g of AIBN. The reaction mixture was heated at 60-75° C. for 5-20 hours. The product was precipitated in ethyl ether or n-hexane, filtered and dried to provide poly [2-(toluene-4-sulfonyloxy)ethyl acrylate/3-hydroxypropyl methacrylate-/methyl methaclylate-/glycidyl methacrylate] represented by the following chemical formula 8, at a yield of 65-70%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06956091B2 |
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| 출처 데이터셋 | uspto-grants-2005_10 |
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| ORD ID | ord-8ce41e99404d42d5af9bb226484dea0b |
|---|
| 출처 메모 | uspto-grants-2005_10 |
|---|
