Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acrolein → Dimethyl 2-formyl-3-methylcyclopropane-1,1-dicarboxylate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acrolein | HCID 7847 | — |
| 반응물 | Hexenal | HCID 10460 | — |
| 반응물 | 2-Pentenal | HCID 12993 | — |
| 반응물 | Crotonaldehyde | HCID 447466 | — |
| 반응물 | Acetic acid trans-4-oxo-but-2-enyl ester | HCID 11535561 | — |
| 생성물 | Dimethyl 2-formyl-3-methylcyclopropane-1,1-dicarboxylate | HCID 12729146 | — |
| 생성물 | Dimethyl 3-(acetoxymethyl)-2-formylcyclopropane-1,1-dicarboxylate | HCID 21312667 | — |
| 생성물 | Dimethyl 2-formyl-3-ethylcyclopropane-1,1-dicarboxylate dimethyl 2-formyl-3-propylcyclopropane-1,1-dicarboxylate | HCID 86736587 | — |
반응 단계
In the same manner but replacing acrolein with an equivalent amount of crotonaldehyde, 2-pentenal, 2-hexenal or γ-acetoxycrotonaldehyde, the following compounds of formula V, dimethyl 2-formyl-3-methylcyclopropane-1,1-dicarboxylate, dimethyl 2-formyl-3-ethylcyclopropane-1,1-dicarboxylate dimethyl 2-formyl-3-propylcyclopropane-1,1-dicarboxylate, dimethyl 3-(acetoxymethyl)-2-formylcyclopropane-1,1-dicarboxylate are obtained, respectively.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04161608 |
| 출처 데이터셋 | uspto-grants-1979_07 |
| ORD ID | ord-88c1e95af60c4d3a85051080473e97f0 |
| 출처 메모 | uspto-grants-1979_07 |