Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Potassium Hydroxide → Glycerol tris[2-hydroxy-3-(7,7,8,9,9-pentamethyl-2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propyl]ether
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 반응물 | Triglycidylglycerol | HCID 25795 | — |
| 반응물 | 7,7,8,9,9-Pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione | HCID 20481853 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | Glycerol tris[2-hydroxy-3-(7,7,8,9,9-pentamethyl-2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propyl]ether | HCID 131711585 | — |
반응 단계
12.0 g of 7,7,8,9,9-pentamethyl-1,3,8-triazaspiro[4.5]-decane-2,4-dione, 4.1 g of glycerol tris(2,3-epoxypropyl)ether and 1.1 g of potassium hydroxide were reacted in 80 ml of methanol, following substantially the same procedure as in Example 1. The desired Compound No. 177 was obtained in the form of a white powder, having an Rf value of 0.45 on thin-layer chromatography on silica gel using a 4:4:4:1:1 by volume mixture of benzene, ethyl acetate, chloroform, methanol and triethylamine as developing solvent.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04162246 |
| 출처 데이터셋 | uspto-grants-1979_07 |
| ORD ID | ord-92d226cb0e284e6eb5648e6b1e540e68 |
| 출처 메모 | uspto-grants-1979_07 |