Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2,2'-((1-Methylethylidene)bis(cyclohexane-4,1-diyloxymethylene))bisoxirane → 2,2-Bis{4-[2-hydroxy-3-(7,7,8,9,9-pentamethyl2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propoxy]cyclohexyl}propane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2,2'-((1-Methylethylidene)bis(cyclohexane-4,1-diyloxymethylene))bisoxirane | HCID 114514 | — |
| 반응물 | 7,7,8,9,9-Pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione | HCID 20481853 | — |
| 생성물 | 2,2-Bis{4-[2-hydroxy-3-(7,7,8,9,9-pentamethyl2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propoxy]cyclohexyl}propane | HCID 20396790 | — |
반응 단계
A mixture of 8 g of 7,7,8,9,9-pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione and 5 g of 2,2-bis[4-(2,3-epoxypropoxy)cyclohexyl]propane was heated at 180°-200° C. for 5 hours. The reaction mixture was then purified by column chromatography through silica gel eluted with a 60:10:1 by volume mixture of ethyl acetate, ethanol and triethylamine and then by recrystallisation from ethyl acetate, giving the desired compound in the form of white crystals melting at 130°-133° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04162246 |
| 출처 데이터셋 | uspto-grants-1979_07 |
| ORD ID | ord-0e42e3277a1d4944b43a1754307a4991 |
| 출처 메모 | uspto-grants-1979_07 |