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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 972031생성일: 2026년 10월 26일

2,2'-((1-Methylethylidene)bis(cyclohexane-4,1-diyloxymethylene))bisoxirane → 2,2-Bis{4-[2-hydroxy-3-(7,7,8,9,9-pentamethyl2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propoxy]cyclohexyl}propane

https://huagongshe.com/reaction/972031

반응식

참여 물질

역할이름HCID투입량
반응물2,2'-((1-Methylethylidene)bis(cyclohexane-4,1-diyloxymethylene))bisoxiraneHCID 114514—
반응물7,7,8,9,9-Pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dioneHCID 20481853—
생성물2,2-Bis{4-[2-hydroxy-3-(7,7,8,9,9-pentamethyl2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propoxy]cyclohexyl}propaneHCID 20396790—

반응 단계

A mixture of 8 g of 7,7,8,9,9-pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione and 5 g of 2,2-bis[4-(2,3-epoxypropoxy)cyclohexyl]propane was heated at 180°-200° C. for 5 hours. The reaction mixture was then purified by column chromatography through silica gel eluted with a 60:10:1 by volume mixture of ethyl acetate, ethanol and triethylamine and then by recrystallisation from ethyl acetate, giving the desired compound in the form of white crystals melting at 130°-133° C.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US04162246
출처 데이터셋uspto-grants-1979_07
ORD IDord-0e42e3277a1d4944b43a1754307a4991
출처 메모uspto-grants-1979_07