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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 972048생성일: 2026년 10월 25일

Potassium Hydroxide → Phosphoric acid, monooctadecyl ester, zinc salt (1:1)

https://huagongshe.com/reaction/972048

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참여 물질

역할이름HCID투입량
반응물Potassium HydroxideHCID 14797—
반응물Zinc SulfateHCID 24424—
반응물CID 21881707HCID 21881707—
용매WaterHCID 962—
생성물Phosphoric acid, monooctadecyl ester, zinc salt (1:1)HCID 165255—

반응 조건

온도90 °C

반응 단계

Water (88 L) was added to stearyl phosphate (molar ratio of diester/monoester=1/2.7; acid value, 232 mg KOH/g) (5 kg) while heating at 90° C., whereby the stearyl phosphate was dispersed uniformly. An aqueous solution of potassium hydroxide (300 g/L) (3862 ml) was dropwise added to the mixture while keeping the said temperature. When the addition was finished, the mixture showed a pH of about 11. The saponified dispersion was divided in five equal parts, and an aqueous solution of zinc sulfate (300 g/L) (1591 ml) was added to each part at 50°, 60°, 70°, 80° or 90° C. and the mixture was further stirred for 90 minutes. The product was collected, washed with water, filtered, dried at 75° C. for 72 hours and pulverized by the aid of a water-cooling type hammer mill to give zinc stearyl phosphate. The results are shown in Table 1.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US04163018
출처 데이터셋uspto-grants-1979_07
ORD IDord-72ccf124566541a194fd5a0814ec8dcb
출처 메모uspto-grants-1979_07