참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 반응물 | Zinc Sulfate | HCID 24424 | — |
| 반응물 | CID 21881707 | HCID 21881707 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Phosphoric acid, monooctadecyl ester, zinc salt (1:1) | HCID 165255 | — |
반응 단계
Water (88 L) was added to stearyl phosphate (molar ratio of diester/monoester=1/2.7; acid value, 232 mg KOH/g) (5 kg) while heating at 90° C., whereby the stearyl phosphate was dispersed uniformly. An aqueous solution of potassium hydroxide (300 g/L) (3862 ml) was dropwise added to the mixture while keeping the said temperature. When the addition was finished, the mixture showed a pH of about 11. The saponified dispersion was divided in five equal parts, and an aqueous solution of zinc sulfate (300 g/L) (1591 ml) was added to each part at 50°, 60°, 70°, 80° or 90° C. and the mixture was further stirred for 90 minutes. The product was collected, washed with water, filtered, dried at 75° C. for 72 hours and pulverized by the aid of a water-cooling type hammer mill to give zinc stearyl phosphate. The results are shown in Table 1.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US04163018 |
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| 출처 데이터셋 | uspto-grants-1979_07 |
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| ORD ID | ord-72ccf124566541a194fd5a0814ec8dcb |
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| 출처 메모 | uspto-grants-1979_07 |
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