Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ammonia → 2,4,6-Triphenylpyridine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ammonia | HCID 222 | — |
| 반응물 | Benzaldehyde | HCID 240 | — |
| 반응물 | Acetophenone | HCID 7410 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 생성물 | 2,4,6-Triphenylpyridine | HCID 136370 | 68% |
반응 단계
"Simple aldehydes and ketones without activating groups require mildly forcing conditions and produce the fully aromatic pyridines; accordingly, acetophenone, benzaldehyde, and ammonia in refluxing acetic acid gave a 68% yield of 2,4,6,-triphenylpyridine and a 25% yield of β-phenylpropionophenone."
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04055588 |
| 출처 데이터셋 | uspto-grants-1977_10 |
| ORD ID | ord-aa7d96fb12664a28b4538204f2d3b683 |
| 출처 메모 | uspto-grants-1977_10 |