Peracetic Acid → HCID 20314474, 화합물

HRID 973310노트

반응식

HRID 973310 반응식
[C:1]([O:4]O)(=[O:3])[CH3:2].[Cl:6][C:7]1[CH:12]=[CH:11][C:10]([C:13]2[CH:18]=[CH:17][C:16]([I:19])=[CH:15][CH:14]=2)=[CH:9][CH:8]=1>C(O)(=O)C>[Cl:6][C:7]1[CH:8]=[CH:9][C:10]([C:13]2[CH:18]=[CH:17][C:16]([I:19]([O:4][C:1](=[O:3])[CH3:2])[O:4][C:1](=[O:3])[CH3:2])=[CH:15][CH:14]=2)=[CH:11][CH:12]=1

참가 물질

4

반응물 2

HCID 6585Peracetic AcidHCID 43042304-Chloro-4'-iodo-1,1'-biphenyl

생성물 1

HCID 20314474HCID 20314474, 화합물

시약·촉매·용매 1

HCID 176Acetic Acid용매

반응 조건

온도
30 °C

실험 절차

Peracetic acid (40%, 13 ml.) is added dropwise to a stirred suspension of 4-(4-chlorophenyl)iodobenzene (12.6 g.) in acetic acid (25 ml.) at 30° C. during 1hour. The mixture is stirred at 30° C. for 6 hours, and at ambient temperature for 2 days, then evaporated to dryness in vacuo. The residue is washed with light petroleum, and is crystallised from chloroform to give 4-(4-chlorophenyl)-(diacetoxyiodo)-benzene (10.7 g.) m.p. 147°-150° C.

후처리

  1. waitat ambient temperature for 2 days
  2. customevaporated to dryness in vacuo
  3. washThe residue is washed with light petroleum
  4. customis crystallised from chloroform

출처 및 근거

ORD 기록
ord-e3efe665b3824f09b6940726e6456629
출처 데이터셋
uspto-grants-1977_10
특허 번호
US04055595

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