2,6-Dimethyloctanoic acid → 2,6-Dimethyl-1-octanol

HRID 973382노트

반응식

HRID 973382 반응식
[H-].[Al+3].[Li+].[H-].[H-].[H-].[CH3:7][CH:8]([CH2:12][CH2:13][CH2:14][CH:15]([CH3:18])[CH2:16][CH3:17])[C:9](O)=[O:10]>CCOCC>[CH3:7][CH:8]([CH2:12][CH2:13][CH2:14][CH:15]([CH3:18])[CH2:16][CH3:17])[CH2:9][OH:10]

참가 물질

4

반응물 2

HCID 122667202,6-Dimethyloctanoic acidHCID 21226445Aluminium lithium hydride

생성물 1

HCID 110082002,6-Dimethyl-1-octanol수율 80%

시약·촉매·용매 1

HCID 3283Diethyl Ether용매

실험 절차

First, 1.9 g (0.05 mol) of lithium aluminum hydride was suspended in 50 ml of dried ether while being cooled on an ice bath. Then, 8.6 g (0.05 mol) of 2,6-dimethyl octanoic acid was dripped into the resultant mixture, while the mixture was being stirred, and was reacted with the mixture for 20 hours, thereby obtaining 6.32 g of 2,6-dimethyl-1-octanol (V) at yield of 80%. This reaction is described as follows: ##STR6##

후처리

  1. temperaturewhile being cooled on an ice bath
  2. customwas reacted with the mixture for 20 hours

출처 및 근거

ORD 기록
ord-1392ef6b8fa44691867a187be7ea19be
출처 데이터셋
uspto-grants-1991_11
특허 번호
US05063058

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