Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methane → 2-(2,6-Dichloro-4-trifluoromethylphenylhydrazono)propanal 1-oxime
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methane | HCID 297 | — |
| 반응물 | Sulfuric acid magnesium salt (1:1) | HCID 24083 | — |
| 반응물 | [2,6-Dichloro-4-(trifluoromethyl)phenyl]hydrazine | HCID 688223 | — |
| 반응물 | 2-Oxopropanal-1-oxime | HCID 6399213 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | 2-(2,6-Dichloro-4-trifluoromethylphenylhydrazono)propanal 1-oxime | HCID 136341205 | — |
반응 단계
A solution of 2,6-dichloro-4-trifluoromethylphenylhydrazine (10.2 g) in ether (15 ml) was added with cooling to a solution of `2-oxopropanal 1-oxime (3.62 g) in ether (15 ml) at 0°. The mixture was stirred at room temperature overnight and magnesium sulphate and charcoal added. The mixture was filtered and solvent evaporated under reduced pressure. The residue was purified by column chromatography to give 2-(2,6-dichloro-4-trifluoromethylphenylhydrazono)propanal 1-oxime, m.p, c.108°.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05064844 |
| 출처 데이터셋 | uspto-grants-1991_11 |
| ORD ID | ord-f5e3e5b3d37946958d7541f859f44bf7 |
| 출처 메모 | uspto-grants-1991_11 |