Benzene → N,N-bis(trimethylsilyl)Methanesulfonamide
반응식
[CH3:1][S:2]([NH2:5])(=[O:4])=[O:3].C(N(CC)CC)C.C1C=CC=CC=1.[CH3:19][Si:20]([CH3:23])([CH3:22])Cl>CCCCCC>[CH3:19][Si:20]([CH3:23])([CH3:22])[N:5]([Si:20]([CH3:23])([CH3:22])[CH3:19])[S:2]([CH3:1])(=[O:4])=[O:3]참가 물질
6
실험 절차
A glass reactor equipped with a stirrer, nitrogen inlet, reflux condenser and addition funnel was purged with nitrogen and charged with 29.1 g (0.30 mol) of methanesulfonamide, MeSO2NH2, where Me represents the methyl radical, 84.9 ml (0.605 mol) of triethylamine and 240 ml of dry benzene. Trimethylchlorosilane (129.5 ml, 1.00 mol) was then added through the addition funnel over a period of 15 minutes to the stirred mixture, followed by heating at the boiling point for three hours. The mixture was then diluted with 200 ml of hexane and stirring was continued for 30 minutes.
후처리
- customA glass reactor equipped with a stirrer, nitrogen inlet
- temperaturereflux
- additioncondenser and addition funnel
- customwas purged with nitrogen
- temperatureby heating at the boiling point for three hours
출처 및 근거
- ORD 기록
- ord-abc4716cdac84c6f91c8dbce364af083
- 출처 데이터셋
- uspto-grants-1991_11
- 특허 번호
- US05068379
반응 노트
불러오는 중…