Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Oxygen → 4-Methylphenyl acetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | Azobisisobutyronitrile | HCID 6547 | — |
| 반응물 | 4-Methylphenyl acetate | HCID 8797 | — |
| 반응물 | 1,3,5-Trihydroxy-1,3,5-triazinane-2,4,6-trione | HCID 10419723 | — |
| 촉매 | Cobalt diacetate | HCID 6277 | — |
| 촉매 | Manganous Acetate | HCID 12525 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 생성물 | 4-Methylphenyl acetate | HCID 8797 | — |
| 생성물 | Benzoic acid, 4-(acetyloxy)- | HCID 16865 | — |
반응 단계
A mixture of 0.300 g of p-tolyl acetate, 0.018 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (5% by mole relative to p-tolyl acetate), 5 g of acetic acid, 0.003 g of cobalt(II) acetate.4H2O, 0.001 g of manganese(II) acetate.4H2O and 0.003 g of 2,2′-azobisisobutyronitrile was stirred at 100° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 6 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield 4-acetoxybenzoic acid in 82% yield at 85% conversion of p-tolyl acetate.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07091342B2 |
| 출처 데이터셋 | uspto-grants-2006_08 |
| ORD ID | ord-6ceb42c45e9a4b67a98dfccbbdb747c4 |
| 출처 메모 | uspto-grants-2006_08 |