Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Potassium Carbonate → 2-(2,4,6-Triiodophenoxy)nonane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | 2,4,6-Triiodophenol | HCID 11862 | — |
| 반응물 | 2-Methanesulfonyloxynonane | HCID 14916006 | — |
| 반응물 | 2-(2,4,6-Triiodophenoxy)pentadecane | HCID 15343309 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | 2-(2,4,6-Triiodophenoxy)nonane | HCID 15343313 | 68% |
반응 단계
The 2-methanesulfonyloxynonane (22.8 g, 102 mmol), triiodophenol (48.8 g, 103 mmol) and potassium carbonate (14.2 g, 103 mmol) were reacted in DMF (206 ml) as per 2-(2,4,6-triiodophenoxy)pentadecane except at an oil bath temperature of 82° C. for 14 hrs. The reaction was processed as for 2-(2,4,6-triiodophenoxy)pentadecane to provide a light brown oil. Flash column chromatography (silica, hexanes) provided 2-(2,4,6-triiodophenoxy)nonane (40.8 g, 68.0%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05607660 |
| 출처 데이터셋 | uspto-grants-1997_03 |
| ORD ID | ord-5924d4a5d885450cb80faddba131a647 |
| 출처 메모 | uspto-grants-1997_03 |