Sodium Iodide → Iodomethyl octyl carbonate

HRID 974767노트

반응식

HRID 974767 반응식
[C:1](=[O:14])([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[O:2][CH2:3]Cl.[I-:15].[Na+]>CC(C)=O>[C:1](=[O:14])([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[O:2][CH2:3][I:15]

참가 물질

4

반응물 2

HCID 5238Sodium IodideHCID 19969190Chloromethyl octyl carbonate

생성물 1

HCID 19969200Iodomethyl octyl carbonate수율 72.6%

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

To a solution of chloromethyl octyl carbonate (1.14 g, 0.005 mol) in acetone (10 ml) was added sodium iodide (2.3 g, 0.015 mol). The mixture was stirred for 3 hours, concentrated invacuo, and dissolved in dichloromethane (50 ml). This solution was washed with saturated aqueous sodium chloride, aqueous sodium thiosulfate, and saturated aqueous sodium chloride, dried (sodium sulfate) and concentrated invacuo to yield iodomethyl octyl carbonate (1.14 g).

후처리

  1. concentrationconcentrated invacuo
  2. dissolutiondissolved in dichloromethane (50 ml)
  3. washThis solution was washed with saturated aqueous sodium chloride, aqueous sodium thiosulfate, and saturated aqueous sodium chloride
  4. dry with materialdried (sodium sulfate)
  5. concentrationconcentrated invacuo

출처 및 근거

ORD 기록
ord-e50a6d5bfbaf43b69f4c60a775680c32
출처 데이터셋
uspto-grants-1997_03
특허 번호
US05607691

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