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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 9751생성일: 2026년 10월 23일

Oxygen → Benzaldehyde

https://huagongshe.com/ko/reaction/9751

반응식

참여 물질

역할이름HCID투입량
반응물OxygenHCID 977—
반응물TolueneHCID 1140—
반응물1,3,5-Trihydroxy-1,3,5-triazinane-2,4,6-trioneHCID 10419723—
촉매Cobalt diacetateHCID 6277—
용매Acetic AcidHCID 176—
생성물BenzaldehydeHCID 240—
생성물Benzoic AcidHCID 243—

반응 단계

A mixture of 0.276 g of toluene, 0.005 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (1% by mole relative to toluene), 5 g of acetic acid and 0.004 g of cobalt(II) acetate.4H2O was stirred at 60° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 6 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield benzoic acid and benzaldehyde in 49% and 3% yields, respectively, at 53% conversion of toluene.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US07091342B2
출처 데이터셋uspto-grants-2006_08
ORD IDord-25be29cbfe4341219e0e5c16fc46daa6
출처 메모uspto-grants-2006_08