Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Acid → Terephthalic Acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | P-Xylene | HCID 7809 | — |
| 반응물 | 1,3,5-Trihydroxy-1,3,5-triazinane-2,4,6-trione | HCID 10419723 | — |
| 촉매 | Cobalt diacetate | HCID 6277 | — |
| 촉매 | Manganous Acetate | HCID 12525 | — |
| 생성물 | Terephthalic Acid | HCID 7489 | 95% |
반응 단계
A mixture of 0.212 g of p-xylene, 0.018 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (5% by mole relative to p-xylene), 5 g of acetic acid, 0.003 g of cobalt(II) acetate.4H2O and 0.003 g of manganese(II) acetate.4H2O was stirred at 100° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 14 hours. The resulting product in the reaction mixture was analyzed by high performance liquid chromatography and was found to yield terephthalic acid in 95% yield at 100% conversion of p-xylene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07091342B2 |
| 출처 데이터셋 | uspto-grants-2006_08 |
| ORD ID | ord-29c4d4a941814f3893092bbee75bd8b4 |
| 출처 메모 | uspto-grants-2006_08 |