HCID 19965658, 화합물 → HCID 19965664, 화합물

HRID 977269노트

반응식

HRID 977269 반응식
[CH3:1][C:2]1[O:6][C:5]([C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=2)=[N:4][C:3]=1[CH2:13][CH2:14][C:15]1[CH:20]=[CH:19][C:18](/[CH:21]=[CH:22]/[CH:23]=[CH:24]/[CH2:25][OH:26])=[CH:17][CH:16]=1>[O-2].[O-2].[Mn+4]>[CH3:1][C:2]1[O:6][C:5]([C:7]2[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=2)=[N:4][C:3]=1[CH2:13][CH2:14][C:15]1[CH:16]=[CH:17][C:18](/[CH:21]=[CH:22]/[CH:23]=[CH:24]/[CH:25]=[O:26])=[CH:19][CH:20]=1

참가 물질

3

반응물 1

HCID 19965658HCID 19965658, 화합물

생성물 1

HCID 19965664HCID 19965664, 화합물

시약·촉매·용매 1

HCID 178418406HCID 178418406, 화합물촉매

실험 절차

(E,E)-5-[4-[2-(5-methyl- 2-phenyl-4-oxazolyl )ethyl]phenyl ]- 2,4-pentadien-1-ol was oxidized with activated manganese dioxide in the same manner as in Reference Example 25 to yield (E,E)-5-[4-[2-(5-methyl-2-phenyl4-oxazolyl)ethyl]phenyl]-2,4-pentadien-1-al, which was then recrystallized from ethyl acetate to yield yellow rods having a melting point of 107°-108° C.

출처 및 근거

ORD 기록
ord-7d5d3c815ce24ec6b1fce3c6c7532bc2
출처 데이터셋
uspto-grants-1997_03
특허 번호
US05614544

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