Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Triphenylphosphine → (8-Tetrahydropyranyloxyoctyl)triphenylphosphonium bromide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Triphenylphosphine | HCID 11776 | — |
| 반응물 | 2H-Pyran, 2-[(8-bromooctyl)oxy]tetrahydro- | HCID 170916 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 생성물 | (8-Tetrahydropyranyloxyoctyl)triphenylphosphonium bromide | HCID 18997637 | — |
반응 단계
A solution of 1-bromo-8-tetrahydropyranyloxyoctane (9.8 g) and triphenyl phosphine (8.8 g) in acetonitrile (50 ml) was heated under reflux for 8 hours. The solution was evaporated and the residue washed with ether to give the title compound as a hygroscopic white solid which was dried by addition of benzene and re-evaporation.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04665189 |
| 출처 데이터셋 | uspto-grants-1987_05 |
| ORD ID | ord-f09819ec5beb460cac605f0a1d570f8f |
| 출처 메모 | uspto-grants-1987_05 |