Quinone → HCID 13853736, 화합물
반응식
[C:1]1(=[O:8])[CH:6]=[CH:5][C:4](=O)[CH:3]=[CH:2]1.[NH2:9][C:10]1[C:15]([O:16][CH3:17])=[CH:14][CH:13]=[CH:12][C:11]=1[SH:18]>CO>[CH3:17][O:16][C:15]1[CH:14]=[CH:13][CH:12]=[C:11]2[C:10]=1[N:9]=[C:4]1[C:3](=[CH:2][C:1](=[O:8])[CH:6]=[CH:5]1)[S:18]2참가 물질
4
실험 절차
To a suspension of p-benzoquinone (3.0 g) in 15 ml methanol was added 2-amino-3-methoxythiophenol (2.2 g) dissolved in 10 ml methanol. The mixture was stirred at room temperature for 45 minutes and concentrated in vacuo. The residue was triturated with ether and filtered. The resulting dark solid was chromatographed on silica gel and eluted with EtOAc, to afford the desired compound, m.p. 206°-207°.
후처리
- concentrationconcentrated in vacuo
- customThe residue was triturated with ether
- filtrationfiltered
- customThe resulting dark solid was chromatographed on silica gel
- washeluted with EtOAc
출처 및 근거
- ORD 기록
- ord-91014a185122430ba7a71587985786f0
- 출처 데이터셋
- uspto-grants-1987_05
- 특허 번호
- US04667032
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