Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2,6-Dichlorophenol → 2-(2-Bromo-1,1,2,3,3,3-hexafluoropropanoxy)-1,3-dichlorobenzene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2,6-Dichlorophenol | HCID 6899 | — |
| 반응물 | Propyl mercaptan | HCID 7848 | — |
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | 1,2-Dibromo-1,1,2,3,3,3-hexafluoropropane | HCID 69579 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | 2-(2-Bromo-1,1,2,3,3,3-hexafluoropropanoxy)-1,3-dichlorobenzene | HCID 20222414 | 84.2% |
반응 단계
In a manner similar to Step A of Example 1, the reaction of 16.3 g (0.10 mole) 2,6-dichlorophenol, 13.8 g (0.10 mole) potassium carbonate, 1.0 g (0.013 mole) propanethiol, 62.0 g (0.20 mole) 1,2-dibromohexafluoropropane, and 125 ml of N,N-dimethylformamide produced 33.0 g of 2-(2-bromo-1,1,2,3,3,3-hexafluoropropanoxy)-1,3-dichlorobenzene as an oil. The ir spectra was consistent with the proposed structure.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04636523 |
| 출처 데이터셋 | uspto-grants-1987_01 |
| ORD ID | ord-27a28549375a4545b65144861ada399d |
| 출처 메모 | uspto-grants-1987_01 |