Sodium thiocyanate → HCID 13107038, 화합물
반응식
Cl.[NH2:2][CH:3]([CH2:21][CH3:22])[C:4]([C:6]1[CH:11]=[C:10]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:9]([OH:16])=[C:8]([C:17]([CH3:20])([CH3:19])[CH3:18])[CH:7]=1)=O.[S-:23][C:24]#[N:25].[Na+]>>[C:17]([C:8]1[CH:7]=[C:6]([C:4]2[NH:25][C:24](=[S:23])[NH:2][C:3]=2[CH2:21][CH3:22])[CH:11]=[C:10]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:9]=1[OH:16])([CH3:20])([CH3:19])[CH3:18]참가 물질
3
실험 절차
By following the same procedure as in Example 8 using 13.1 g of 2-amino-1-(3,5-di-tert-butyl-4-hydroxyphenyl)-1-butanone hydrochloride, 6.5 g of sodium thiocyanate, 3.4 ml of concentrated, and 100 ml of acetic acid and recrystallizing the reaction product from isopropanol, 6 g of 4-(3,5-di-tert-butyl-4-hydroxyphenyl)-5-ethyl-2-thioxo-4-imidazoline was obtained.
후처리
- concentrationof concentrated
- custom100 ml of acetic acid and recrystallizing the reaction product from isopropanol
출처 및 근거
- ORD 기록