Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium Sulfate → 1-Dodecylazepane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium Sulfate | HCID 24436 | — |
| 반응물 | Laurocapram | HCID 42981 | — |
| 반응물 | Aluminium lithium hydride | HCID 21226445 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | 1-Dodecylazepane | HCID 3366129 | 93.5% |
반응 단계
56.2g (0.2 mol) of 1-dodecylazacycloheptan-2-one in 100ml diethyl ether was added dropwise to a suspension of 7.6g (0.2 mol) lithium aluminum hydride in 100ml diethyl ether under argon at room temperature. After 5 hours of stirring, 20ml saturated sodium sulfate was added dropwise. The mixture was filtered and the filtrate was dried with magnesium sulfate, filtered and concentrated. The resulting oil was distilled (130°/0.03 mm) to yield 50.03g (93.5%) of 1-n-dodecylazacycloheptane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04992422 |
| 출처 데이터셋 | uspto-grants-1991_02 |
| ORD ID | ord-a4ab3fbc760d4c649a4daf7fb67026be |
| 출처 메모 | uspto-grants-1991_02 |