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Ethylene → Ethylene/propylene 5-vinyl-2-norbornene 5-ethylidene-2-norbornene

HRID 983566
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인쇄 미리보기

반응식

HRID 983566 반응식
C=C.[CH2:3]=[CH:4]C.[CH:6]([CH:8]1[CH2:13][CH:12]2[CH2:14][CH:9]1[CH:10]=[CH:11]2)=[CH2:7].[CH:15](=[C:17]1[CH2:22][CH:21]2[CH2:23][CH:18]1[CH:19]=[CH:20]2)[CH3:16].[H][H].[Al](Cl)(CC)CC>CCCCCC>[CH2:3]=[CH2:4].[CH2:7]=[CH:6][CH3:8].[CH:15]([CH:17]1[CH2:22][CH:21]2[CH2:23][CH:18]1[CH:19]=[CH:20]2)=[CH2:16].[CH:6](=[C:8]1[CH2:13][CH:12]2[CH2:14][CH:9]1[CH:10]=[CH:11]2)[CH3:7]
참가 물질실험 절차출처 및 근거반응 노트

참가 물질

8

반응물 6

HCID 6325Ethylene2회HCID 7277Diethylaluminum chlorideHCID 8252Propylene2회HCID 182735-Vinyl-2-norbornene2회HCID 27756Ethylidenenorbornene2회HCID 178418361HCID 178418361, 화합물

생성물 1

HCID 86599656
Ethylene/propylene 5-vinyl-2-norbornene 5-ethylidene-2-norbornene

시약·촉매·용매 1

HCID 8058Hexane용매

실험 절차

In a 100-liter stainless steel polymerization reactor equipped with a stirring blade (number of stirring revolutions: 250 rpm), tetrapolymerization of ethylene, propylene, 5-vinyl-2-norbornene and 5-ethylidene-2-norbornene was continuously carried out. To the liquid phase in the reactor were fed hexane at a rate of 60 l/hr, ethylene at a rate of 3.0 kg/hr, propylene at a rate of 8.5 kg/hr, 5-vinyl-2-norbornene at a rate of 370 g/hr and 5-ethylidene-2-norbornene at a rate of 470 g/hr, and were further continuously fed hydrogen at a rate of 50N l /hr and as catalysts VOCl3 at a rate of 90 mmol/hr, Al(Et)2Cl at a rate of 420 mmol/hr and Al(Et)1.5Cl1.5 at a rate of 120 mmol/hr, through the side inlet of the reactor.

출처 및 근거

ORD 기록
ord-3056d5ca017040b190b4e0d999e74520
출처 데이터셋
uspto-grants-2005_03
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06864315B1

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