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Ethylene → ethylene/propylene VNB

HRID 983567
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인쇄 미리보기

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HRID 983567 반응식
C=C.[CH2:3]=[CH:4]C.[CH:6]([CH:8]1[CH2:13][CH:12]2[CH2:14][CH:9]1[CH:10]=[CH:11]2)=[CH2:7].[H][H].[Al](Cl)(CC)CC>CCCCCC>[CH2:3]=[CH2:4].[CH2:7]=[CH:6][CH3:8].[CH:6]([CH:8]1[CH2:13][CH:12]2[CH2:14][CH:9]1[CH:10]=[CH:11]2)=[CH2:7]
참가 물질실험 절차출처 및 근거반응 노트

참가 물질

7

반응물 5

HCID 6325Ethylene2회HCID 7277Diethylaluminum chlorideHCID 8252PropyleneHCID 182735-Vinyl-2-norborneneHCID 178418361HCID 178418361, 화합물

생성물 1

HCID 86599654ethylene/propylene VNB

시약·촉매·용매 1

HCID 8058
Hexane
용매

실험 절차

In a 100-liter stainless steel polymerization reactor equipped with a stirring blade (number of stirring revolutions: 250 rpm), terpolymerization of ethylene, propylene and 5-vinyl-2-norbornene was continuously carried out. To the liquid phase in the reactor were fed hexane at a rate of 60 l/hr, ethylene at a rate of 3.8 kg/hr, propylene at a rate of 9.2 kg/hr and 5-vinyl-2-norbornene at a rate of 120 g/hr, and were further continuously fed hydrogen at a rate of 30 l/hr and as catalysts VOCl3 at a rate of 18 mmol/hr, Al(Et)2Cl at a rate of 90 mmol/hr and Al(Et)1.5Cl1.5 at a rate of 18 mmol/hr, through the side inlet of the reactor.

출처 및 근거

ORD 기록
ord-dcb2671f90ae424492bc6193eed4b46e
출처 데이터셋
uspto-grants-2005_03
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06864315B1

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