Diisobutylaluminum hydride → (E)-3-(2'-methyl-biphenyl-4-yl)-but-2-en-1-ol

HRID 984356노트

반응식

HRID 984356 반응식
CC(C[AlH]CC(C)C)C.[CH3:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[C:17]1[CH:22]=[CH:21][C:20](/[C:23](/[CH3:30])=[CH:24]/[C:25](OCC)=[O:26])=[CH:19][CH:18]=1>>[CH3:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[C:17]1[CH:18]=[CH:19][C:20](/[C:23](/[CH3:30])=[CH:24]/[CH2:25][OH:26])=[CH:21][CH:22]=1

참가 물질

3

반응물 2

HCID 14487Diisobutylaluminum hydrideHCID 22557711(E)-ethyl 3-(2'-methyl-biphenyl-4-yl)-but-2-enoate

생성물 1

HCID 22557657(E)-3-(2'-methyl-biphenyl-4-yl)-but-2-en-1-ol

실험 절차

The colourless oil (E)-3-(2′-methyl-biphenyl-4-yl)-but-2-en-1-ol was prepared by DIBAL-H reduction of (E)-ethyl 3-(2′-methyl-biphenyl-4-yl)-but-2-enoate by a procedure analogous to that described in example 50b.

출처 및 근거

ORD 기록
ord-41bc202b34404362b88808e0356c3410
출처 데이터셋
uspto-grants-2005_03
특허 번호
US06867218B2

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