Benzyl 4-Hydroxybenzoate → Di(p-benzyloxycarbonylphenyl)sebacate

HRID 986518

반응식

[OH:1][C:2]1[CH:17]=[CH:16][C:5]([C:6]([O:8][CH2:9][C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[O:7])=[CH:4][CH:3]=1.[C:18](Cl)(=[O:30])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][C:27](Cl)=[O:28]>>[CH2:9]([O:8][C:6]([C:5]1[CH:16]=[CH:17][C:2]([O:1][C:18](=[O:30])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][C:27]([O:1][C:2]2[CH:3]=[CH:4][C:5]([C:6]([O:8][CH2:9][C:10]3[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=3)=[O:7])=[CH:16][CH:17]=2)=[O:28])=[CH:3][CH:4]=1)=[O:7])[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

참가 물질

반응물 2

HCID 7180Benzyl 4-Hydroxybenzoate

HCID 66072Sebacoyl chloride

생성물 1

HCID 13822727Di(p-benzyloxycarbonylphenyl)sebacate

실험 절차

A similar procedure to Example 1 is carried out by using 16.7 g of benzyl p-hydroxybenzoate and 16.7 g of sebacic acid dichloride to yield di(p-benzyloxycarbonylphenyl)sebacate, m.p. 62.5°-63° C., as white crystals.

출처 및 근거

ORD 기록: ord-4f5406523af2423da21f14648aa9e4e5
출처 데이터셋: uspto-grants-1987_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04713474

연결된 노트

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