1-Bromohexadecane → HCID 15141162, 화합물

HRID 987347노트

반응식

HRID 987347 반응식
Br[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].[OH:18][C:19]1[CH:20]=[C:21]([CH:24]=[C:25]([OH:28])[C:26]=1[OH:27])[CH:22]=[O:23]>>[CH2:2]([O:18][C:19]1[CH:20]=[C:21]([CH:24]=[C:25]([O:28][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH3:2])[C:26]=1[O:27][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH3:2])[CH:22]=[O:23])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

참가 물질

3

반응물 2

HCID 82131-BromohexadecaneHCID 836513,4,5-Trihydroxybenzaldehyde

생성물 1

HCID 15141162HCID 15141162, 화합물

실험 절차

The title compound was prepared according to the method as described in Example 9 above from 1-bromohexadecane and 3,4,5-trihydroxy-benzaldehyde, except the reaction mixture was heated at reflux for 4 days. After cooling, the solid material was removed by filtration and the solid washed with dichloromethane. The combined organic extracts were evaporated under reduced pressure to yield the title compound which was recrystallised from dichloromethane-ethanol.

후처리

  1. customThe title compound was prepared
  2. temperaturewas heated
  3. temperatureat reflux for 4 days
  4. temperatureAfter cooling
  5. customthe solid material was removed by filtration
  6. washthe solid washed with dichloromethane
  7. customThe combined organic extracts were evaporated under reduced pressure

출처 및 근거

ORD 기록
ord-4081cdd73fc04656868dbfaefafb1f6a
출처 데이터셋
uspto-grants-2003_10
특허 번호
US06630128B1

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