Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Tributylstannane → Bis[1-(3-hydroxypropoxy)-2,2,6,6-tetramethylpiperidin-4-yl]Sebacate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Tributylstannane | HCID 5948 | — |
| 반응물 | Heptane | HCID 8900 | — |
| 반응물 | 3-Bromo-1-propanol | HCID 12308 | — |
| 반응물 | Bis(1-hydroxy-2,2,6,6-tetramethyl-4-piperidinyl)decandioate | HCID 11272241 | — |
| 반응물 | Ethylacetate heptane | HCID 21899848 | — |
| 용매 | Chlorobenzene | HCID 7964 | — |
| 생성물 | Bis[1-(3-hydroxypropoxy)-2,2,6,6-tetramethylpiperidin-4-yl]Sebacate | HCID 22507641 | — |
반응 단계
Tributyltin hydride is added dropwise to a solution of 3-bromo-1-propanol and excess bis(1-oxyl-2,2,6,6tetramethylpiperidin-4-yl)sebacate in chlorobenzene. The mixture is heated to facilitate reaction. The crude reaction mixture is passed through silica gel with heptane and then heptane/ethyl acetate to afford the title compound.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06638997B2 |
| 출처 데이터셋 | uspto-grants-2003_10 |
| ORD ID | ord-ccea7a570720437abf2466ed87690ea6 |
| 출처 메모 | uspto-grants-2003_10 |