Nitric Acid → p-Anisidine, 2,6-dinitro-

HRID 992069노트

반응식

HRID 992069 반응식
[N+:1]([O-:4])([OH:3])=O.[CH3:5][O:6][C:7]1[CH:12]=[CH:11][C:10]([NH2:13])=[C:9]([N+:14]([O-:16])=[O:15])[CH:8]=1>>[CH3:5][O:6][C:7]1[CH:12]=[C:11]([N+:1]([O-:4])=[O:3])[C:10]([NH2:13])=[C:9]([N+:14]([O-:16])=[O:15])[CH:8]=1

참가 물질

3

반응물 2

HCID 944Nitric AcidHCID 667934-Methoxy-2-nitroaniline

생성물 1

HCID 138470p-Anisidine, 2,6-dinitro-수율 53%

실험 절차

To a stirred solution of HNO3 (65 mL) was added 4-methoxy-2-nitro-phenylamine (15 g, 89.3 mmol). The reaction mixture was stirred at room temperature overnight. The dark red precipitate was filtered and washed with H2O (400 mL) affording 10.01 g (53%) of the title compound.

후처리

  1. filtrationThe dark red precipitate was filtered
  2. washwashed with H2O (400 mL)

출처 및 근거

ORD 기록
ord-41ac04f3b79b4280a102d9b13547b319
출처 데이터셋
uspto-grants-2002_10
특허 번호
US06465482B2

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