Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Acid → 1-Nitroadamantane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | Adamantane | HCID 9238 | — |
| 반응물 | N-Hydroxyphthalimide | HCID 10665 | — |
| 생성물 | 1-Nitroadamantane | HCID 64165 | 64% |
반응 단계
Into a flask, 1 mmole of adamantane, 0.1 mmole of N-hydroxyphthalimide and 6 ml of acetic acid were added to mix. The flask was purged by nitrogen monoxide NO (about 1L) and oxygen O2 (about 1L), and then the mixture was reacted for 20 hours at 110° C. with stirring. The reaction products were analyzed by gas chromatography, and, as a result, the conversion of adamantane was 90%, and 1-nitroadamantane (yield 64%) and 1,3-dinitroadamantane (yield 12%) were formed.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06468487B1 |
| 출처 데이터셋 | uspto-grants-2002_10 |
| ORD ID | ord-aec03bee9da5464ca1e458d8bae2b610 |
| 출처 메모 | uspto-grants-2002_10 |