Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Oxygen → 1-Nitroadamantane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Oxygen | HCID 977 | — |
| 반응물 | (Trifluoromethyl)benzene | HCID 7368 | — |
| 반응물 | Adamantane | HCID 9238 | — |
| 반응물 | N-Hydroxyphthalimide | HCID 10665 | — |
| 반응물 | Nitrogen Dioxide | HCID 178526396 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 생성물 | 1-Adamantanol | HCID 64152 | 2% |
| 생성물 | 1-Nitroadamantane | HCID 64165 | 73% |
| 생성물 | 1-Adamantyl acetate | HCID 519973 | 1% |
반응 단계
Into a flask, 1 mmole of adamantane, 0.05 mmole of N-hydroxyphthalimide, 15 mmole of nitrogen dioxide (NO2), 1 ml of acetonitrile and 2 ml of trifluoromethylbenzene were added and stirred for 5 hours at 60° C. in an atmosphere of oxygen. The reaction products were analyzed by gas chromatography, and, as a result, the conversion of adamantane was 90%, and nitroadamantane (yield 73%), adamantanol (yield 2%), acetyloxyadamantane (yield 1%) and adamantanone (yield 3%) were formed.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06468487B1 |
| 출처 데이터셋 | uspto-grants-2002_10 |
| ORD ID | ord-684f6da515db4ca99b2f29e56dd22d9f |
| 출처 메모 | uspto-grants-2002_10 |