Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Acid → 3-Nitrotricyclo(3.3.1.13,7)decane-1-carboxylic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Acid | HCID 176 | — |
| 반응물 | N-Hydroxyphthalimide | HCID 10665 | — |
| 반응물 | 1-Adamantanecarboxylic acid | HCID 13235 | — |
| 생성물 | 3-Nitrotricyclo(3.3.1.13,7)decane-1-carboxylic acid | HCID 39239 | 80% |
반응 단계
Into a flask, 1 mmole of 1-carboxyadamantane, 0.1 mmole of N-hydroxyphthalimide and 6 ml of acetic acid were added to mix. The mixture was purged by nitrogen monoxide NO (about 1L) and oxygen O2 (about 1L), and then reacted for 20 hours at 110° C. with stirring. The reaction products were analyzed by gas chromatography, and, as a result, the conversion of 1-carboxyadamantane was 90%, and 1-carboxy-3-nitroadamantane (yield 80%) was formed.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06468487B1 |
| 출처 데이터셋 | uspto-grants-2002_10 |
| ORD ID | ord-dfd3540c043044058646b3a81bad990c |
| 출처 메모 | uspto-grants-2002_10 |