Aluminium lithium hydride → HCID 54546588, compound

HRID 1004616Notes

Reaction equation

HRID 1004616 reaction equation
[H-].[H-].[H-].[H-].[Li+].[Al+3].[CH2:7]([N:14]1[C@H:22]2[C@@H:17]([CH2:18][C:19]3[CH:26]=[CH:25][CH:24]=[C:23]([O:27][CH3:28])[C:20]=3[CH2:21]2)[CH2:16][C:15]1=O)[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>>[CH2:7]([N:14]1[C@H:22]2[C@@H:17]([CH2:18][C:19]3[CH:26]=[CH:25][CH:24]=[C:23]([O:27][CH3:28])[C:20]=3[CH2:21]2)[CH2:16][CH2:15]1)[C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 53849263HCID 53849263, compound

Product 1

HCID 54546588HCID 54546588, compound

Procedure

0.21 g (5.5 mmol) of LiAlH4 and 0.5 g (1.6 mmol) of trans-(±)-1-benzyl-8-methoxy-2, 3,3a,4,9,9a-hexahydro-1H-benz[f]indol-2-one (8a) are used. Yield: 0.4 g (85%).

Sources & evidence

ORD record
ord-013fc36d09ca47488f4bd585d4fa2299
Source dataset
uspto-grants-2000_04
Patent number
US06051583

Reaction notes

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