Lithium, mol. (Li2) → HCID 178461103, compound

HRID 1004855Notes

Reaction equation

HRID 1004855 reaction equation
[Cl-:1].[Cl-].[C:3](=[Zr+2:6]([CH:20]1[C:28]2[C:23](=[CH:24][CH:25]=[CH:26][CH:27]=2)[C:22]([Si](C)(C)C)=[CH:21]1)[CH:7]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[C:9]([Si](C)(C)C)=[CH:8]1)([CH3:5])[CH3:4].C[Si](C)(C)[C:35]1[C:43]2C(=CC=CC=2)C(C(C2C3C(=CC=CC=3)C([Si](C)(C)C)=C2)(C)C)[CH:36]=1.[Li][Li].[CH:64](C1C2C(=CC=CC=2)C(C(C2C3C(=CC=CC=3)C(C(C)C)=C2)(C)C)C=1)([CH3:66])[CH3:65]>>[Cl-:1].[Cl-:1].[C:3](=[Zr+2:6]([CH:20]1[C:28]2[C:23](=[CH:24][CH:25]=[CH:26][CH:27]=2)[C:22]([CH:64]([CH3:66])[CH3:65])=[CH:21]1)[CH:7]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[C:9]([CH:35]([CH3:43])[CH3:36])=[CH:8]1)([CH3:5])[CH3:4]

Participants

5

Reactant 4

HCID 139759Lithium, mol. (Li2)HCID 18670031HCID 18670031, compoundHCID 22595380HCID 22595380, compoundHCID 178461106HCID 178461106, compound

Product 1

HCID 178461103HCID 178461103, compound

Procedure

It was worked according to the procedure described at point (c) of example 1 except that, instead of 2,2-bis(3-trimethylsilyl-indenyl)propane, 20 mmol of the dilithium salt of 2,2-bis(3-isopropyl-indenyl)propane was used, and that the product was recrystallized from DME. Pure rac-isopropylidene-bis(3-isopropyl-indenyl)zirconium dichloride was obtained. 1H-NMR (toluene-d8, 30° C.) δ: 7.34 (m.4H); 6.98 (m,2H); 6,69 (m,2H); 5.78 (s,2H); 3.14 (sept,2H); 1.81 (s,6H); 1.20 (d,12H).

Workup

  1. customthat the product was recrystallized from DME

Sources & evidence

ORD record
ord-ba018752f6d9438da238498955ada6e4
Source dataset
uspto-grants-2000_04
Patent number
US06051728

Reaction notes

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