HRID1005332

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID176

Acetic Acid

C2H4O2

HCID72861

Xanthydrol

C13H10O2

结构：CCOC(=O)CC(=O)C1CC(C(=O)OCCC(=O)c2ccccc2)C1

HCID18791135

未命名化合物

PRODUCTS

生成物

结构：CCOC(=O)C(C(=O)C1CC(C(=O)OCCC(=O)c2ccccc2)C1)C1c2ccccc2Oc2ccccc21

HCID18791133

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

Acetic acid (20 ml) was added to a stirred suspension of 9-hydroxyxanthene (3.96 g, 20 mmol) and ethyl 3-oxo-3-[3-(phenacylmethyloxycarbonyl) cyclobutyl]propanate (6.0 g, 18 mmol) in ethanol (20 ml) at room temperature. A clear solution formed and was allowed to stand for 7 days at room temperature.

WORKUP

后处理

customA clear solution formed

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d2a13ead311f457bbe212e4d69a20f70
来源数据集: uspto-grants-2000_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06054448
来源说明: uspto-grants-2000_04

反应 SMILES

C(O)(=O)C.O[CH:6]1[C:19]2[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=2[O:13][C:12]2[C:7]1=[CH:8][CH:9]=[CH:10][CH:11]=2.[O:20]=[C:21]([CH:28]1[CH2:31][CH:30]([C:32]([O:34][CH2:35][CH2:36][C:37]([C:39]2[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=2)=[O:38])=[O:33])[CH2:29]1)[CH2:22][C:23]([O:25][CH2:26][CH3:27])=[O:24]>C(O)C>[CH:18]1[C:19]2[CH:6]([CH:22]([C:21](=[O:20])[CH:28]3[CH2:31][CH:30]([C:32]([O:34][CH2:35][CH2:36][C:37]([C:39]4[CH:40]=[CH:41][CH:42]=[CH:43][CH:44]=4)=[O:38])=[O:33])[CH2:29]3)[C:23]([O:25][CH2:26][CH3:27])=[O:24])[C:7]3[C:12](=[CH:11][CH:10]=[CH:9][CH:8]=3)[O:13][C:14]=2[CH:15]=[CH:16][CH:17]=1