HRID1007116

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：COc1ccc(P2(=S)SP(=S)(c3ccc(OC)cc3)S2)cc1

HCID87949

p-Anisyldithiophosphonic anhydride

C14H14O2P2S4

结构：CC(C)OC(=O)N1CC(=O)Nc2ccc(-c3cccc(Cl)c3)cc21

HCID22667742

未命名化合物

PRODUCTS

生成物

结构：CC(C)OC(=O)N1CC(=S)Nc2ccc(-c3cccc(Cl)c3)cc21

HCID22667725

未命名化合物

PROCEDURE

实验过程

Prepared according to the procedure for Example 24 from isopropyl 7-(3-chlorophenyl)-3-oxo-3,4-dihydroquinoxaline-1(2H)-carboxylate and Lawesson's reagent. A yellowish solid: m.p. 208-212° C.; 1H-NMR (DMSO-d6) δ 1.27 (d, J=6.1 Hz, 6H), 4.62 (s, 2H), 4.94 (sep, J=6.1 Hz, 1H), 7.23 (m, 4H), 7.64 (t, J=1.8 Hz, 1H), 7.90 (s, 1H), 12.80 (s, 1H), MS (ESI) m/z 359/361 (M−H)-.

WORKUP

后处理

customPrepared